ナカライテスク株式会社

Cosmosil

COSMOSIL PBB

  • HPLC/UHPLC
特長
  • 3 種のフラーレン専用カラムの中で最も保持力の大きいカラムです。
  • o - ジクロロベンゼンなどのトルエンよりも溶解性の高い溶媒中で分離可能で、大量分取精製に最適です。
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製品使用例

各溶媒中での高次フラーレンの分離

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Conditions
Column COSMOSIL 5PBB
Mobilephase o-Dichlorobenzene
Detection UV 310 nm

 

Pbb-10_c_2.gif
Conditions
Column COSMOSIL 5PBB
Mobilephase 1,2,4-Trichlorobenzene
Detection UV 310 nm

 

Pbb-10_c_3.gif
Conditions
Column COSMOSIL 5PBB 
Mobilephase Carbon Disulfide
Detection UV 380 nm

 

Conditions
Column size 4.6 mm I.D. × 250 mm Temperature 30℃
Flow rate 1.0 mL/min Sample C60, C70, C76, C84

フラーレンの大量分取精製

C60 とC70 の精製において、Buckyprep の約 3 倍の分取精製が可能です。

Pbb-tairyoubunsyu.jpg
Conditions
Column COSMOSIL 5PBB
20 mm I.D. × 250 mm
Temperature Room Temperature
Mobilephase Toluene Detection UV 285 nm
Flow rate 18 mL/min Sample Crude Fullerene 3.5 mg/mL

使用文献

  • Li Qu, Wenbin Cao, Gengmei Xing, Jun Zhang, Hui Yuan, Jun Tang, Yue Cheng, Bo Zhang, Yuliang Zhao, and Hao Lei. Study of rare earth encapsulated carbon nanomolecules for biomedical uses. Journal of Alloys and Compounds , 408-412, 2006, 400-404.
  • James C. Duchamp, Aline Demortier, Kerra R. Fletcher, Daniel Dorn, Erick B. Iezzi, Tom Glass and Harry C. Dorn. An isomer of the endohedral metallofullerene Sc3N@C80 with D5h symmetry. Chemical Physics Letters , 375(5-6), 2003, 655-659.
  • I. N. Ioffe, A. S. Ievlev, O. V. Boltalina, L. N. Sidorov, H. C. Dorn, S. Stevenson and G. Rice. Electron affinity of some trimetallic nitride and conventional metallofullerenes. International Journal of Mass Spectrometry, 213(2-3), 2002, 183-189.
  • J. R. Baena, M. Gallego and M. Valcarcel. Fullerenes in the analytical sciences. TrAC Trends in Analytical Chemistry , 21(3), 2002, 187-198.
  • Kazuhiko Akiyama, Keisuke Sueki, Takeshi Kodama, Koichi Kikuchi, Yasutaka Takigawa, Hiromichi Nakahara, Isao Ikemoto and Motomi Katada. New fullerenes of a group IV element: Hf metallofullerenes. Chemical Physics Letters, 317(3-5), 2000, 490-496.
  • H Shinohara. Endohedral metallofullerenes. Rep. Prog. Phys., 63, 2000, 843-892.
  • Koichi Kikuchi, Kazuhiko Akiyama, Koichi Sakaguchi, Takeshi Kodama, Hiroyuki Nishikawa, Isao Ikemoto, Toshinobu Ishigaki, Yohji Achiba, Keisuke Sueki and Hiromichi Nakahara. Production and isolation of the isomers of dimetallofullerenes, HoTm@C82 and Tm2@C82. Chemical Physics Letters , 319(5-6), 2000, 472-476.
  • Takeshi Akasakaa, Shingo Okubo, Masahiro Kondo, Yutaka Maeda, Takatsugu Wakahara, Tatsuhisa Kato, Toshiyasu Suzuki, Kazunori Yamamoto, Kaoru Kobayashi and Shigeru Nagase. Isolation and characterization of two Pr@C82 isomers. Chemical Physics Letters , 319(1-2), 2000, 153-156.
  • Keisuke Sueki, Kouichi Kikuchi, Kazuhiko Akiyama, Tomomi Sawa, Motomi Katada, Shizuko Ambe, Fumitoshi Ambe and Hiromichi Nakahara. Formation of metallofullerenes with higher group elements. Chemical Physics Letters, 300(1-2), 1999, 140-144.
  • J. R. Heflin, D. Marciu, C. Figura, and S. Wang, P. Burbank, S. Stevenson, and H. C. Dorn. Enhanced nonlinear optical response of an endohedral metallofullerene through metal-to-cage charge transfer. Applied Physics Letters, 72(22), 1998, 2788-2790.
  • M. Rubsam, P. Schweitzer and K. -P. Dinse. Nuclear quadrupole interaction in Sc@C82. Chemical Physics Letters , 263(3-4), 1996, 540-544.
  • K Kimata, T Hirose, K Moriuchi, K Hosoya, T Araki and N.Tanaka. High-capacity stationary phases containing heavy atoms for HPLC separation of fullerenes. Analytical Chemistry, 67, 1995, 2556-2561.
  • T. Hirata, R. Suzuki and R. Hatakeyama. Formation of novel Si-fullerene compound materials using a high-density silicon-ion plasma. Thin Solid Films, 515(9), 4177-4181.

価格表

分析・分取カラム(粒子径 5 µm)
COSMOSIL 5PBB

製品名 サイズ 製品番号 オンラインカタログへ
COSMOSIL 5PBB Guard Column 4.6 mm l.D. × 10 mm 37987-31 e-Nacalai.jpg
10 mm l.D. × 20 mm 37988-21 e-Nacalai.jpg
20 mm l.D. × 50 mm 34375-31 e-Nacalai.jpg
COSMOSIL 5PBB Packed Column 4.6 mm l.D. × 250 mm 37980-01 e-Nacalai.jpg
10 mm l.D. × 250 mm 37985-51 e-Nacalai.jpg
20 mm l.D. × 250 mm 37986-41 e-Nacalai.jpg

※上記以外のカラムサイズをご要望の際はお問い合わせください。

※掲載内容は予告なく変更になる場合があります。